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Re: Axial chirality [message #1070 is a reply to message #1066] Sun, 13 September 2020 12:04 Go to previous messageGo to previous message
thomas is currently offline  thomas
Messages: 715
Registered: June 2014
Senior Member
Axial chirality (indicated as M or P) is covered to some extend:

- For allenes the configuration is assigned to the central atom.
- In case of atropisomers only bi-phenyls with at least three ortho substituents
are considered because of the reliably hindered rotation. Here the central bond
carries the configuration information.

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